Optimizing sugar ratios for macaron taste and structure
Abstract:
Macaron recipes are numerous and varied in their recommendations for amounts of almond flour,
sugars, and egg whites. Particularly, recipes vary in their ratios of confectioners’ sugar to granulated
sugar. Sugar is a key component in macaron shells as it contributes both to flavor and structure of the
finished product. While it is commonly assumed that granulated sugar functions to strengthen the
meringue while confectioners’ sugar contributes to lightness of texture and formation of the macaron
“foot,” little empirical evidence is available to support these claims. In this study, various sugar ratios
will be tested to determine effects on macaron structure and taste; macaron shells will be qualitatively
evaluated based on commonly acknowledged structural features: symmetry and height of the foot, shell
surface, interior structure, texture, and smoothness of bottom. In addition, shells will be assessed based
on taste and functionality when assembled using a simple ganache-based filling. The goal is to
determine the ideal sugar ratio that will yield macarons with an optimal structure and flavor profile.
Introduction:
The French macaron has garnered much popularity in recent years. A sweet, meringue-based confection,
the classic French macaron recipe consists of almond flour, granulated sugar, egg whites, and
confectioners’ sugar. Macarons are commonly filled with jams, ganaches, or buttercreams; the finished
macaron consists of a sandwich of two shells stacked with tops facing outward and the filling acting as
an edible “glue” in between, much like an Oreo. As the macaron has grown in popularity, there have
been increasing efforts among baking enthusiasts and macaron-lovers to elucidate the recipe “secrets”
that will produce macaron-perfection.
A macaron is essentially a meringue-based cookie. It contains no baking soda or baking powder, and
achieves rise upon baking due to steam released from the whipped egg whites. A properly formed
macaron features a flat base, a frilly edge around the base referred to as the “foot,” and a smooth,
glossy top (Fig 1). The texture of the shell should be light and airy with a slight chew, but not tough. A
cross-section should yield an even, spongy structure with no obvious air pocket between the surface and
the rest of the shell. The standard size for a macaron shell is roughly 3.00-5.00 centimeters in diameter
and 0.75-1.00 centimeters in height.
Variation in recipes
While only four ingredients make up the basic macaron recipe, variations range impressively across
blogs, books, and magazines. A fundamental distinction among recipes is that of the French vs. Italian
Meringue. The Italian Meringue consists of a sugar syrup that is created through bringing sugar to a boil
with water to create a hot syrup, which is drizzled into the egg whites as they beat into a meringue,
producing a glossier, more stable foam. The French Meringue, on the other hand, does not require
heating of the sugar; egg whites are beaten until foamy and granulated sugar is slowly incorporated as
the whites continue to get beaten until it forms a stable meringue. While both recipes yield decent
products, restaurants tend to prefer the Italian Meringue method for its consistency. For the purposes
of this study, variations on the French Meringue recipe will be tested, as it is the method more
commonly used among bakers at home.
Table 1 summarizes some of the most commonly cited variables in macaron recipes. Variations
range from those involving ingredients – i.e. consistency of almond flour – to those involving equipment
– i.e. double vs. single baking sheet – to those involving technique – i.e. measuring ingredients by
volume or by weight.
Technical considerations take center stage in the majority of articles on macaron recipe
optimization. By contrast, much of the literature has little to offer on the extensive variation found
across recipes with regard to ingredient ratios. A sampling of macaron recipes was taken from wellfrequented
blogs and websites, and ingredients were normalized to reflect relative mass per gram of
egg white (Table 2). While proportions of almond flour per gram of egg white remained similar across
recipes (range 0.76-1.30, average 1.10, std. dev. 0.17), proportions of confectioners’ sugar and
granulated sugar exhibited greater inter-recipe variation (range 1.30-2.25, std. dev. 0.30; range 0.25-
1.20, std. dev. 0.29). When recipes were plotted according to the ratio of total sugar mass to almond
flour mass, however, many of the ratios fell within the same range (Fig 2).
Much of the variation across recipes, therefore, appears to stem from variation in ratios of
confectioners’ to granulated sugar. To further assess these differences, the relative proportion of each
type of sugar to 1 gram of egg white was plotted graphically to generate a regression that exhibited a
moderately strong inverse relationship between proportions of each sugar (Fig 3).
These observations highlight sugar proportions as a key point of variation with potential for
recipe optimization. Developing a better understanding of how variation in sugar proportions affects
macaron taste and structure will facilitate one’s ability to reproduce the ideal macaron.
Science of the Meringue
Sugar in macaron shells contributes not only to flavor, but also to structure. A critical step in macaron
making is the beating of egg whites to form a medium-stiff meringue. Harold McGee describes a
meringue as an “egg white foam”: upon beating, egg white proteins unfold and join together to form a
“reinforcing network” consisting of “bonds between positively and negatively charged parts of
molecules, between water-like parts, between fat-like pars, and between sulfur groups.”
A medium-stiff meringue forms soft yet sturdy peaks. Structurally, this is the point at which egg
white proteins have formed just enough bonds with each other to form loose “cages” around water
droplets present in the mixture, creating a stable matrix of water droplets held within a protein
structure. When overbeaten, egg white proteins develop too many bonds with each other, causing the
protein cages to become too tight and to “squeeze” the water droplets out of the matrix, resulting in
separation of egg whites from the moisture in the foam.
Various tactics are employed to stabilize a meringue. One strategy is to introduce sugar into the
mix. Sugar helps “stabilize the egg-white foam by increasing the viscosity of the water present in the
foam,” making the foam thicker and less likely to collapse when folded in with other ingredients.2
Additionally, one can prevent overbeating by introducing agents that interfere with bond-formation.
One option is to use metal ions to disrupt sulfur bonding. French bakers have a history of using copper
bowls for making meringues, a technique rooted in good chemical sense: copper ions have a tendency
to form tight bonds with reactive sulfur groups, effectively preventing egg whites from binding too
tightly to each other to cause separation of proteins from moisture in a meringue.3 Another option is to
use acid to interfere with protein-protein interactions: the addition of a small amount of acid (such as
lemon juice or cream of tartar) increases the number of hydrogen ions in the mixture, which interact
with free sulfur groups to decrease S-S binding.4
Other tips in macaron recipes involve using room temperature whites, aging egg whites, and
avoiding contact with oils and other hydrophobic materials. Room temperature whites facilitate protein
unraveling to form networks in which water droplets can be suspended. The process of aging egg whites
involves placing egg whites in a clean bowl covered with a paper towel or other breathable covering,
and letting some of the moisture evaporate from the egg whites for a period ranging from 24 hours to 5
days. The goal of aging is to concentrate the egg proteins so that a stronger meringue can be created
upon beating. Avoiding hydrophobic agents such as oils and plastic bowls (which tend to bind oils)
ensures that such molecules do not interfere with the protein-air-water interface and hinder foam formation.
Aims
The goal of the proposed study was to determine the effects of manipulating sugar proportions on
macaron taste and structure. Specifically, this study aimed to assess how a high proportion of
granulated sugar vs. a high proportion of powdered sugar would affect the final product with regard to
the following specifications: symmetry and height of the foot, texture of the shell surface, interior
structure, texture, and smoothness of bottom.
Discussion
Both granulated and confectioners’ sugars contribute critically to macaron taste and structure. This
qualitative study demonstrated the merits and detriments of both extremes with regard to proportions
of each sugar. Overall, the high granulated sugar recipe (Recipe A) produced a stiffer meringue that,
when mixed with the dry ingredients, yielded a sturdier batter and subsequently a stronger macaron.
However, Recipe A suffered from impaired rise in the oven, possibly due to the effects of increased
viscosity and stiffness of the protein network upon addition of more granulated sugar to the meringue.
By contrast, the high powdered sugar recipe (Recipe B) produced more rise, yielding a taller and more
symmetrical foot that was more aesthetically pleasing. However, the overall texture of Recipe B
macarons was compromised by the large air pocket that formed with baking, possibly due to the weaker
meringue.
Future studies may consider an intermediate ratio of granulated to confectioners’ sugar,
perhaps testing a 1:5 ratio (1.25 almond : 2.0 confectioners’ : 1.0 egg white : 0.4 granulated).
Experiments from this study suggested that a stronger meringue is a key component of sturdier
macarons. To achieve strength in the meringue without sacrificing rise in the oven, one may consider
using a copper bowl or adding a small amount of lemon juice as insurance against overbeating the egg
whites while still achieving medium-stiff peaks that do not collapse upon incorporation with dry
ingredients. A quantitative analysis (i.e. average foot height, density, individual shell mass) can be
considered in addition to qualitative assessments.
This qualitative study is among several of its kind in the ongoing effort among self-taught bakers
and macaron-enthusiasts to optimize the basic French macaron recipe. The author hopes that such
endeavors will continue to be undertaken to generate reproducible results with increasing consistency
across home kitchens.
http://www.cookingscienceguy.com/pages/wp-content/uploads/2012/07/Food-Science-Macaron3.pdf
Hello mcakes,
Don't despair! I shall do everything in my humble power to help you in your quest for the perfect macaron. What chefs don't usually reveal about macarons using the Italian meringue method are the following:
There really is only one universal formula in terms of the almond - powdered sugar - granulated sugar ratio. It is 1 : 1 : 1.
The only variable is the egg white content. It can go as low as 60 % the weight of the almonds to as high as 90 % the weight of the almonds.
A formula with a low egg white content (60 % to 70 %) results in a very crumbly finished product that stales quickly. the macarons may look fantastic but it is the eating quality and shelf life that is compromised. The only advantage of a low egg white content is that it allows the macarons to be baked without the drying process since there is very little moisture in the batch. But this hardly makes up for the inferior outcome.
A formula with a medium egg white content (71 % to 80 %) produces, in my opinion, the perfect consistency of the finished product....with a thin, egg shell-like crust and a really chewy interior.
A formula with a high egg white content (81 % to 90 %) produces too soft a final product. Once the shells absorb moisture from the filling, they turn almost soggy, which destroys the eating experience.
Looking at your formula, I can see that your egg whites are at 64 %, which is quite low.
However, egg white content is not the only basis for a successful macaron. The procedure has a lot to do with it. Here are some pointers.
Always use aged egg whites. In my experience, I used to get the lopsided macarons back in the days when I used fresh egg whites. My post above has the procedure for ageing egg whites.
Always cook the syrup to 118 degrees Celsius. Cooking at a lower temperature does not stabilize the meringue enough.
After adding the syrup to the egg whites, cool the meringue to 50 degrees Celsius. Never cool it completely. There is a reason for this. Folding the very warm meringue to the TPT does something to the powdered sugar's crystalline structure. It allows the piped macarons to form really nice thin skins that dry up fast and produce magnificent feet. Professional chefs here in Manila always compliment me for my macarons' high feet. A simple way to illustrate this principle is in a simple doughnut glaze recipe. Try making doughnut glaze (powdered sugar and water) using room temperature water and warm water. You will see that the warm water formula produces a better glaze...firm on the outside but nice and soft inside. Same is true when making fondant glaze for Eclairs.
In the macaronage step, agitate the mixture just until it forms a nice thick ribbon when you lift your spatula. In my observation, a lot of chefs over-agitate their macaronage to get to that "LAVA" consistency.
Bake your macarons at 180 degrees Celsius (conventional oven) or 165 degrees Celsius (convection oven). This might be a little high compared to most recipes out there but your need a hot oven to make your macarons literally jump up and form those coveted feet.
https://cheftalk.com/threads/macaron-shell-recipe-italian-meringue-method.74812/